Product Details of 17927-65-0. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Aluminum(III) sulfate xhydrate, is researched, Molecular Al2H8O13S3, CAS is 17927-65-0, about Deuterium/hydrogen fractionation in sulfate hydrate-water systems. Author is Pradhananga, Trinetra M.; Matsuo, Sadao.
The D/H fractionation factors (α) of some of the sulfate hydrate-H2O systems were measured. A dependence of α on cationic parameters and M-H2O distance was found. The D/H fractionation factors of various hydrate-water systems were divided into 2 groups with respect to their α values: one having α < 1 and the other α > 1. There is almost no change in α for crystal-H2O systems having SO42- as the anion of the 1st transition metal ion series from Fe2+ to Zn2+, except for Cu2+. This is related to the common structure of the hydration sphere of cations and the common distance of M-H2O. The exceptional case for Cu2+ is attributed to the distorted structure of octahedra surrounding Cu2+. A similar type of behavior of protons leading to the residual entropy was found in some of the crystal-H2O systems having α > 1.
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