The origin of a common compound about 560-09-8

After consulting a lot of data, we found that this compound(560-09-8)Related Products of 560-09-8 can be used in many types of reactions. And in most cases, this compound has more advantages.

Usami, Atsushi; Motooka, Ryota; Miyazawa, Mitsuo published an article about the compound: (1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid( cas:560-09-8,SMILESS:CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O ).Related Products of 560-09-8. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:560-09-8) through the article.

To clarify the structures of biotransformation products and metabolic pathways, the biotransformation of monoterpenoids, (+)- and (-)-camphorquinone (1a and b), has been investigated using Aspergillus wentii as a biocatalyst. Compound 1a was converted to (-)-(2S)-exo-hydroxycamphor (2a), (-)-(2S)-endo-hydroxycamphor (3a), (-)-(3S)-exo-hydroxycamphor (4a), (-)-(3S)-endo-hydroxycamphor (5a), and (+)-camphoric acid (6a). Compound 1b was converted to (+)-(2R)-exo-hydroxycamphor (2b), (+)-(2R)-endo-hydroxycamphor (3b), (+)-(3R)-exo-hydroxycamphor (4b), (+)-(3R)-endo-hydroxycamphor (5b), and (-)-camphoric acid (6b). Compound 1a mainly produced 2a (65.0%) with stereoselectivity, whereas 1b afforded 3b (84.3%) with high stereoselectivity. These structures were confirmed by gas chromatog.-mass spectrometry, IR, 1H NMR (NMR), and 13C NMR spectral data. The products illustrate the marked ability of A. wentii for enzymic oxidation and ketone reduction

After consulting a lot of data, we found that this compound(560-09-8)Related Products of 560-09-8 can be used in many types of reactions. And in most cases, this compound has more advantages.

Reference:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com