Authors Qi, Y; Zhang, F; Wang, L; Feng, AL; Zhu, RX; Sun, ST; Li, W; Liu, L in ROYAL SOC CHEMISTRY published article about ASYMMETRIC 1,6-CONJUGATE ADDITION; ENANTIOSELECTIVE SYNTHESIS; EXPEDIENT ACCESS; TRIARYLMETHANES; ADDITION/AROMATIZATION; CHEMISTRY; POLYMERS; ACID in [Qi, Yue; Wang, Lin; Li, Wei] Shandong Univ Tradit Chinese Med, Sch Pharm, Dept Pharmaceut Anal, Jinan 250355, Peoples R China; [Feng, Aili; Zhu, Rongxiu; Sun, Shutao; Liu, Lei] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China; [Zhang, Fang] Shandong First Med Univ, Jinan Cent Hosp, Dept Pharm, Jinan 250013, Peoples R China in 2020, Cited 54. SDS of cas: 151-10-0. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0
para-Quinone methides bearing an electron-withdrawing cyano group at the exocyclic methylene delta-position were identified as valuable 1,6-conjugate addition building blocks for acyclic all-carbon quaternary stereocenter construction. A wide variety of electron-rich arenes as nucleophiles were tolerated, effectively furnishing diverse unsymmetrical triarylmethanes bearing all-carbon quaternary stereocenters. The robust transformable abilities of the cyano group provide a platform to access other valuable functional group-containing unsymmetrical tri- and tetraarylmethanes that are otherwise difficult to be prepared. Computational studies supported the hypothesis that the cyano group at the delta-position tunes the molecular electron-density distribution, and the stability of para-quinone methides is enhanced by lowering their polymerizability.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com