I found the field of Chemistry very interesting. Saw the article Selectively Oxidative C(sp(2))-H/C(sp(3))-H Cross-Coupling of Benzamides with Amides by Nickel Catalysis published in 2020.0. Quality Control of 3-Methylbenzoic acid, Reprint Addresses Zhang, YH (corresponding author), Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China.; Han, DM (corresponding author), Taizhou Univ, Dept Chem, Jiaojiang 318000, Peoples R China.. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid
The oxidative cross-coupling between the alpha-C(sp(3))-H bond of amide in DMAc and the inert ortho-C(sp(2))-H bond of benzamides is achieved for the first time by nickel catalysis, with the assistance of 8-aminoquinolyi group in the presence of a silver oxidant. Notably, the selectivity of conversion can be perfectly controlled by modulating the oxidant additives, and the products from the coupling of the C(sp(3))-H bond adjacent to nitrogen of amides with benzamides are approached through the use of peroxide.
Quality Control of 3-Methylbenzoic acid. Welcome to talk about 99-04-7, If you have any questions, you can contact Lv, NN; Yu, SL; Hong, C; Han, DM; Zhang, YH or send Email.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com