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The direct C-H arylation and acylation of azoles with carboxylic acids were achieved through Pd/Cu cooperative catalysis. Various biaryls and biaryl ketones were selectively produced in good to high yields from the same substrates. The key factor of high chemoselectivity was the choice of a suitable phosphine ligand: biaryls were generated selectively with dppp as the ligand, while biaryl ketones were obtained with high selectivity using dpph or Ph2PCy as the ligand.
Welcome to talk about 99-04-7, If you have any questions, you can contact Xiang, K; Zhang, S; Liu, L; Huang, TZ; Tang, Z; Li, CY; Xu, KQ; Chen, TQ or send Email.. Recommanded Product: 3-Methylbenzoic acid
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com