Recently I am researching about ARYLBORONIC ACIDS; ARYL; CONSTRUCTION; CONVERSION; MECHANISM; ALKENYL; LIGAND; ROUTE, Saw an article supported by the School of Pharmaceutical Science and Technology (SPST), Tianjin University, P. R. China; Tianjin Young 1000-Talents Program. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Pei, XC; Zhou, G; Li, XJ; Xu, YC; Panicker, RC; Srinivasan, R. The CAS is 151-10-0. Through research, I have a further understanding and discovery of 1,3-Dimethoxybenzene. Application In Synthesis of 1,3-Dimethoxybenzene
A mild one-pot protocol for the synthesis of symmetrical biaryls by sequential Ir-catalyzed C-H borylation and Cu-catalyzed homocoupling of arenes is described. The regiochemistry of the biaryl formed is sterically controlled as dictated by the C-H borylation step. The methodology is also successfully extended to heteroarenes. Some of the products obtained by this approach are impossible to obtain via the Ullmann or the Suzuki coupling protocols. Finally, we have shown a one-pot sequence describing C-H borylation/Cu-catalyzed homocoupling/Pd-catalyzed Suzuki coupling to obtain pi-extended arene frameworks.
Welcome to talk about 151-10-0, If you have any questions, you can contact Pei, XC; Zhou, G; Li, XJ; Xu, YC; Panicker, RC; Srinivasan, R or send Email.. Application In Synthesis of 1,3-Dimethoxybenzene
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com