Recently I am researching about COBALT; FUNCTIONALIZATION; ALKENYLATION; HYDRAZINES; AMINATION; ARYLATION; CLEAVAGE; INDOLES, Saw an article supported by the DST, CSIR [02(0256)/16EMR-II]; DST, SERB [EMR-II/2017/001475]; University Grants Commission, Government of IndiaUniversity Grants Commission, India. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Sagara, PS; Siril, PF; Ravikumar, PC. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid. Recommanded Product: 3-Methylbenzoic acid
We report a new application of N-amino-7-azaindole as a new bidentate-directing group for [Ru(p-cymene)Cl-2](2)-catalyzed C(sp(2))-H alkenylation/annulation of N-(1H-pyrrolo[2,3-b]pyridin-1-yl)benzamides with internal alkynes to afford N-isoquinolono-7-azaindole via the formation of C-C and C-N bonds. The reaction shows a wide range of substrate scope with different symmetrical and unsymmetrical alkynes, affording the desired product in good to excellent yields. In the case of unsymmetrical alkynes, a highly regioselective product was obtained, which was confirmed by single-crystal X-ray crystallography. A new ruthenium-4-methyl-N-(1H-pyrrolo[2,3-b]pyridin-1-yl)benzamide complex was isolated, and its structure was confirmed by single-crystal X-ray crystallography.
Welcome to talk about 99-04-7, If you have any questions, you can contact Sagara, PS; Siril, PF; Ravikumar, PC or send Email.. Recommanded Product: 3-Methylbenzoic acid
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com