An article Nitromethane as a surrogate cyanating agent: 7-N,N-dimethylamino-4-hydroxycoumarin-catalyzed, metal-free synthesis of alpha-iminonitriles WOS:000599653300019 published article about C-H CYANATION; CATALYZED CYANATION; ARYL BROMIDES; NITRILES; TRANSFORMATION; ISOCYANIDE; CLEAVAGE; ARENES; BONDS; NITROGENATION in [Satyanarayana, Iddum; Yang, Ding-Yah] Tunghai Univ, Dept Chem, 1727,Sec 4,Taiwan Blvd, Taichung 40704, Taiwan; [Manjappa, Kiran B.; Yang, Ding-Yah] Tunghai Univ, Grad Program Biomed & Mat Sci, 1727,Sec 4,Taiwan Blvd, Taichung 40704, Taiwan in 2020.0, Cited 59.0. Application In Synthesis of 2,5-Dimethoxybenzaldehyde. The Name is 2,5-Dimethoxybenzaldehyde. Through research, I have a further understanding and discovery of 93-02-7
An efficient, metal/alkali-cyanide free approach for the synthesis of alpha-iminonitriles via kinetically controlled, base-mediated and 1,3-diketone-catalyzed reaction is reported. The preparation of target compounds was realized by condensation of substituted anilines and aldehydes in nitromethane as a surrogate cyanating agent and as a solvent. This strategy was further improved by replacing aldehydes and nitromethane with beta-nitrostyrene and ethanol, respectively, rendering the methodology greener. The catalytic role played by 1,3-diketones such as 7-N,N-dimethylamino-4-hydroxycoumarin in this three-component reaction was investigated, and a plausible mechanism was proposed based on control experiments.
Application In Synthesis of 2,5-Dimethoxybenzaldehyde. About 2,5-Dimethoxybenzaldehyde, If you have any questions, you can contact Satyanarayana, I; Manjappa, KB; Yang, DY or concate me.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com