Bi, XF; Feng, J; Xue, XP; Gu, ZH in [Bi, Xiufen; Feng, Jia; Xue, Xiaoping; Gu, Zhenhua] Univ Sci & Technol China, Ctr Excellence Mol Synth, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China; [Bi, Xiufen; Feng, Jia; Xue, Xiaoping; Gu, Zhenhua] Univ Sci & Technol China, Ctr Excellence Mol Synth, Dept Chem, Hefei 230026, Anhui, Peoples R China; [Gu, Zhenhua] Minjiang Univ, Ocean Coll, Fuzhou 350108, Fujian, Peoples R China published Construction of Axial Chirality and Silicon-Stereogenic Center via Rh-Catalyzed Asymmetric Ring-Opening of Silafluorenes in 2021, Cited 67. Recommanded Product: 93-97-0. The Name is Benzoic anhydride. Through research, I have a further understanding and discovery of 93-97-0.
A rhodium-catalyzed enantioselective ring-opening/acylation of silafluorenes is reported. The newly developed bulky phosphoramidite ligand, in combination with methanol as the additive, enabled the reaction to create one axial chirality and one silicon-stereogenic center in a highly selective manner by only cleavage of one Si-C bond.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com