An article Construction of Azacycles by Intramolecular Amination of Organoboronates and Organobis(boronates) WOS:000649477300029 published article about CHIRAL SYNTHESIS; ORGANIC AZIDES; ORGANOBORANES; PYRROLIDINE; PIPERIDINE; AMINES; PYRIDINE in [Xu, Peilin; Zhang, Mingkai; Ingoglia, Bryan; Morken, James P.] Boston Coll, Merkert Chem Ctr, Dept Chem, Boston, MA 02467 USA; [Allais, Christophe; Dechert-Schmitt, Anne-Marie R.; Singer, Robert A.] Pfizer Worldwide Res & Dev, Groton, CT 06340 USA in 2021, Cited 42. Category: isothiazole. The Name is Benzoic anhydride. Through research, I have a further understanding and discovery of 93-97-0
Intramolecular amination of organoboronates occurs with a 1,2-metalate shift of an aminoboron ate complex to form azetidines, pyrrolidines, and piperidines. Bis(boronates) undergo site-selective amination to form boronate-containing azacycles. Enantiomerically enriched azacycles are formed with high stereospecificity.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com