An article Annulative pi-Extension of Unactivated Benzene Derivatives through Nondirected C-H Arylation WOS:000485089300084 published article about ION MOBILITY; RAPID ACCESS; FUNCTIONALIZATION; MECHANISM; SOLVENT; SITE in [Lee, Jae Bin; Jeon, Min Ho; Hong, Sung You] UNIST, Sch Energy & Chem Engn, 50 UNIST Gil, Ulsan 44919, South Korea; [Seo, Jeong Kon] UNIST Cent Res Facil, Ulsan 44919, South Korea; [von Helden, Gert] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany; [Rohde, Jan-Uwe; Zhao, Bum Suk] UNIST, Dept Chem, Ulsan 44919, South Korea; [Seo, Jongcheol] POSTECH, Dept Chem, Pohang 37673, South Korea in 2019, Cited 48. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0. Name: 1,3-Dimethoxybenzene
Annulative pi-extension chemistry provides a concise synthetic route to polycyclic arenes. Herein, we disclose a nondirected annulation approach of unactivated simple arenes. The palladium-catalyzed 2-fold C-H arylation event facilitates tandem C-C linkage relays to furnish fully benzenoid triphenylene frameworks using cyclic diaryliodonium salts. The inseparable regioisomeric mixture of 1- and 2-methyltripheny-lenes is identified by the combined analysis of ion mobility-mass spectrometry, gas-phase infrared spectroscopy, and molecular simulation studies.
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Reference:
Isothiazole – Wikipedia,
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