Daley, RA; Liu, EC; Topczewski, JJ in [Daley, Ryan A.; Liu, En-Chih; Topczewski, Joseph J.] Univ Minnesota Twin Cities, Dept Chem, Minneapolis, MN 55455 USA published Additive-Free Palladium-Catalyzed Decarboxylative Cross-Coupling of Aryl Chlorides in 2019, Cited 44. Recommanded Product: 385-00-2. The Name is 2,6-Difluorobenzoic acid. Through research, I have a further understanding and discovery of 385-00-2.
The cross-coupling of sodium (hetero)aryl carboxylates with (hetero)aryl chlorides proceeds with 1 mol % palladium catalyst and does not require inorganic base, silver salts, or copper salts. This coupling uses two low energy partners, and the only stoichiometric byproducts are carbon dioxide and sodium chloride. The substrate scope includes less activated aryl chlorides and carboxylates (>25 examples). The palladium loading could be reduced to 0.1 mol %, and Buchwald-style precatalysts could be used.
Recommanded Product: 385-00-2. Welcome to talk about 385-00-2, If you have any questions, you can contact Daley, RA; Liu, EC; Topczewski, JJ or send Email.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com