An article Synthetic Approach to the ABCD Ring System of Anticancer Agent Fredericamycin A via Claisen Rearrangement and Ring-Closing Metathesis as Key Steps WOS:000492429100004 published article about DIELS-ALDER REACTION; STRATEGY; MODEL; BIOSYNTHESIS; POLYCYCLICS; DERIVATIVES; PROTOCOL; DESIGN in [Kotha, Sambasivarao; Cheekatla, Subba Rao; Fatma, Ambareen] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India in 2019.0, Cited 68.0. The Name is 2,5-Dimethoxybenzaldehyde. Through research, I have a further understanding and discovery of 93-02-7. Application In Synthesis of 2,5-Dimethoxybenzaldehyde
A new synthetic strategy to the ABCD ring system of the anticancer agent fredericamycin A (NSC-305263) was realized by the Diels-Alder reaction and olefin metathesis as key steps. The tactics developed here for the construction of the ABCD ring system also involve double Claisen rearrangement followed by a retro-Diels-Alder reaction and ring-closing metathesis. The metathesis approach performs a key role in the construction of A and D rings of the ABCD core unit. More importantly, ABCD fragment synthesis was accomplished without the involvement of protecting groups.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com