In 2019 ORG LETT published article about CATALYZED TRIFLUOROMETHYLATION; MEDIATED TRIFLUOROMETHYLATION; RADICAL-ADDITION; FUNCTIONALIZATION; DEHYDROGENATION; RENAISSANCE; AMINES; METAL in [Jud, Wolfgang; Maljuric, Snjezana; Kappe, C. Oliver; Cantillo, David] Karl Franzens Univ Graz, Inst Chem, NAWI Graz, Heinrichstr 28, A-8010 Graz, Austria; [Jud, Wolfgang; Maljuric, Snjezana; Kappe, C. Oliver; Cantillo, David] Res Ctr Pharmaceut Engn GmbH RCPE, Ctr Continuous Flow Synth & Proc CC FLOW, Inffeldgasse 13, A-8010 Graz, Austria in 2019, Cited 46. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0. Quality Control of 1,3-Dimethoxybenzene
While several trifluoromethylation reactions involving the electrochemical generation of CF3 radicals via anodic oxidation have been reported, the alternative cathodic, reductive radical generation has remained elusive. Herein, the first cathodic trifluoromethylation of arenes and heteroarenes is reported. The method is based on the electrochemical reduction of an unstable triflyltriethylammonium complex generated in situ from inexpensive triflyl chloride and triethylamine, which produces CF3 radicals that are trapped by the arenes on the cathode surface.
Quality Control of 1,3-Dimethoxybenzene. Welcome to talk about 151-10-0, If you have any questions, you can contact Jud, W; Maljuric, S; Kappe, CO; Cantillo, D or send Email.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com