New explortion of 3-Methylbenzoic acid

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SDS of cas: 99-04-7. In 2020 TETRAHEDRON published article about C-H-BENZOXYLATION; AMMONIUM-NITRATE; CATALYZED ACYLOXYLATION; BOND FUNCTIONALIZATIONS; O-BENZOXYLATION; AROMATIC-ACIDS; ACETOXYLATION; C(SP(3))-H; SP(2); 2-ARYLPYRIDINES in [Yong, Jia-Yuan; Huu-Manh Vu; Li, Xu-Qin; Gong, Ai-Jun] Univ Sci & Technol Beijing, Sch Chem & Biol Engn, 30 Xueyuan Rd, Beijing 100083, Peoples R China in 2020, Cited 77. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7.

Palladium (0)-catalyzed Ortho-benzoxylation of the sp(2) C-H bond of arylbenzoxazinones with carboxylic acid is reported. With benzoxazinone as directing group, the reaction went smoothly under the benign condition and gave the desired product with excellent ortho selectivity. This procedure is compatible with a wide range of functional groups without the use of any ligands or additives. This method provides a straightforward and convenient access to various valuable acyloxylated products. (C) 2020 Elsevier Ltd. All rights reserved.

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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com