Something interesting about 385-00-2

SDS of cas: 385-00-2. About 2,6-Difluorobenzoic acid, If you have any questions, you can contact Daley, RA; Topczewski, JJ or concate me.

SDS of cas: 385-00-2. Daley, RA; Topczewski, JJ in [Daley, Ryan A.; Topczewski, Joseph J.] Univ Minnesota, Dept Chem, Minneapolis, MN 44544 USA published Palladium-catalyzed salt-free double decarboxylative aryl allylation in 2019, Cited 26. The Name is 2,6-Difluorobenzoic acid. Through research, I have a further understanding and discovery of 385-00-2.

This report describes a palladium-catalyzed decarboxylative aryl allylation between unactivated benzoic acids and allylic carbonates. This transformation successfully couples a variety of carbonates and benzoic acids in good yield (up to 94%) using 1 mol% palladium. This salt free allyl-arylation proceeds without added base, copper, or silver. The only stoichiometric byproducts are carbon dioxide and tert-butanol.

SDS of cas: 385-00-2. About 2,6-Difluorobenzoic acid, If you have any questions, you can contact Daley, RA; Topczewski, JJ or concate me.

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com