Authors Massolo, E; Pirola, M; Puglisi, A; Rossi, S; Benaglia, M in ROYAL SOC CHEMISTRY published article about BETA-ENAMINO ESTERS; ENANTIOSELECTIVE REDUCTION; ASYMMETRIC HYDROSILYLATION; RATIONAL DESIGN; AMINES; PERSPECTIVE; DERIVATIVES; SELECTIVITY; AMIDATION; LIGANDS in [Massolo, Elisabetta; Pirola, Margherita; Puglisi, Alessandra; Rossi, Sergio; Benaglia, Maurizio] Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy in 2020, Cited 42. Product Details of 93-97-0. The Name is Benzoic anhydride. Through research, I have a further understanding and discovery of 93-97-0
A two-step one pot, experimentally simple protocol, based on readily available and inexpensive reagents allowed the conversion of nitro-arenes directly to N-aryl amides. A metal-free reduction of the nitro group, mediated by trichlorosilane, followed by the addition of an anhydride afforded the corresponding N-aryl carboxyamide, that was isolated after a simple aqueous work up in good-excellent yields. When the methodology was applied to the reaction with gamma-butyrolactone, the desired N-aryl butanamide derivative was obtained, featuring a chlorine atom at the gamma-position, a functionalized handle that can be used for further synthetic manipulation of the reaction product. Such an intermediate has already been employed as a key advanced precursor of pharmaceutically active compounds.
About Benzoic anhydride, If you have any questions, you can contact Massolo, E; Pirola, M; Puglisi, A; Rossi, S; Benaglia, M or concate me.. Product Details of 93-97-0
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com