HPLC of Formula: C14H10O3. Chuentragool, P; Yadagiri, D; Morita, T; Sarkar, S; Parasram, M; Wang, Y; Gevorgyan, V in [Chuentragool, Padon; Yadagiri, Dongari; Morita, Taiki; Sarkar, Sumon; Parasram, Marvin; Wang, Yang; Gevorgyan, Vladimir] Univ Illinois, Dept Chem, 845 W Taylor St,Rm 4500, Chicago, IL 60607 USA published Aliphatic Radical Relay Heck Reaction at Unactivated C(sp(3))-H Sites of Alcohols in 2019, Cited 59. The Name is Benzoic anhydride. Through research, I have a further understanding and discovery of 93-97-0.
The Mizoroki-Heck reaction is one of the most efficient methods for alkenylation of aryl, vinyl, and alkyl halides. Given its innate nature, this protocol requires the employment of compounds possessing a halogen atom at the site of functionalization. However, the accessibility of organic molecules possessing a halogen atom at a particular site in aliphatic systems is extremely limited. Thus, a protocol that allows a Heck reaction to occur at a specific nonfunctionalized C(sp(3))-H site is desirable. Reported here is a radical relay Heck reaction which allows selective remote alkenylation of aliphatic alcohols at unactivated beta-, gamma-, and delta-C(sp(3))-H sites. The use of an easily installed/removed Si-based auxiliary enables selective I-atom/radical translocation events at remote C-H sites followed by the Heck reaction. Notably, the reaction proceeds smoothly under mild visible-light-mediated conditions at room temperature, producing highly modifiable and valuable alkenol products from readily available alcohols feedstocks.
HPLC of Formula: C14H10O3. About Benzoic anhydride, If you have any questions, you can contact Chuentragool, P; Yadagiri, D; Morita, T; Sarkar, S; Parasram, M; Wang, Y; Gevorgyan, V or concate me.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com