Recently I am researching about C-H AMINATION; ORGANIC-SYNTHESIS; IODINE(V) REAGENTS; BORONIC ACIDS; BRONSTED ACID; BONDS; DELIVERY; NITROSOBENZENES; HETEROCYCLES; DERIVATIVES, Saw an article supported by the SERB, DST, India [ECR/2018/000098]; IIT Ropar; UGC, New DelhiUniversity Grants Commission, India; Indian Institute of Technology, Ropar. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Pradhan, S; Roy, S; Ghosh, S; Chatterjee, I. The CAS is 151-10-0. Through research, I have a further understanding and discovery of 1,3-Dimethoxybenzene. Recommanded Product: 151-10-0
A metal-free aromatic electrophilic substitution reaction using nitrosoarenes as the electrophile in 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) is reported. HFIP activates nitrosoarene towards the electrophilic C-H amination followed by a concomitant N-O bond cleavage to deliver diarylamines without requiring any extra reagent or further treatment. The dual electrophilic nature of nitrosoarene permits a switchover of selectivity to C-H oxygenation furnishing dearomatizedp-iminoquinones following a unique mechanistic rationale of two consecutive [2,3] sigmatropic rearrangement in nitroso-chemistry.
Recommanded Product: 151-10-0. About 1,3-Dimethoxybenzene, If you have any questions, you can contact Pradhan, S; Roy, S; Ghosh, S; Chatterjee, I or concate me.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com