An article Magnesiation of Aryl Fluorides Catalyzed by a Rhodium-Aluminum Complex WOS:000550639000004 published article about C-F BOND; ACTIVATION REACTIONS; CARBON-SULFUR; METAL BONDS; NICKEL; INTERMEDIATE; REACTIVITY; REAGENTS; BEARING; COBALT in [Li, Qiao-Zhi; Sakaki, Shigeyoshi] Kyoto Univ, Fukui Inst Fundamental Chem, Kyoto 6068103, Japan; [Fujii, Ikuya; Semba, Kazuhiko; Nakao, Yoshiaki] Kyoto Univ, Dept Mat Chem, Grad Sch Engn, Kyoto 6158510, Japan in 2020, Cited 74. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. Computed Properties of C8H8O2
We report the magnesiation of aryl fluorides catalyzed by an Al-Rh heterobimetallic complex. We show that the complex is highly reactive to cleave the C-F bonds across the polarized Al-Rh bond under mild conditions. The reaction allows the use of an easy-to-handle magnesium powder to generate a range of arylmagnesium reagents from aryl fluorides, which are conventionally inert to such metalation compared with other aryl halides.
About 3-Methylbenzoic acid, If you have any questions, you can contact Fujii, I; Semba, K; Li, QZ; Sakaki, S; Nakao, Y or concate me.. Computed Properties of C8H8O2
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com