Recently I am researching about N-C CLEAVAGE; ELECTRONICALLY-ACTIVATED AMIDES; METAL-FREE TRANSAMIDATION; PD-NHC PRECATALYST; SECONDARY AMIDES; GENERAL-METHOD; DECARBONYLATIVE BORYLATION; EFFICIENT SYNTHESIS; BOND-CLEAVAGE; ESTERIFICATION, Saw an article supported by the Science and Technology Planning Project of Guangdong Province [2017A010103017]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21272080]; Cultivation Foundation of South China Normal University for Young Teachers [17KJ05]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Li, Y; Wu, HX; Zeng, Z. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid. Safety of 3-Methylbenzoic acid
The first fluoride and palladium co-catalyzed conversion of amide to ester through an aerobic oxidative coupling pathway is reported. This new approach presents a practical process that employs easily available oxygen and commercially available arylboronic acids as coupling partners, uses a wide range of N- tosylamides, and proceeds under mild reaction conditions. This protocol demonstrates broad functional group tolerance, and provides an alternative option to synthesize esters from N-tosylamides which obtained by simply N-functionalization of secondary amides.
About 3-Methylbenzoic acid, If you have any questions, you can contact Li, Y; Wu, HX; Zeng, Z or concate me.. Safety of 3-Methylbenzoic acid
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com