In chemical reaction engineering, simulations are useful for investigating and optimizing a particular reaction process or system. 14489-75-9, Name is N-Methyl-1-(naphthalen-1-yl)methanamine, SMILES is C1=CC=CC2=C1C(=CC=C2)CNC, in an article , author is Kunugi, A, once mentioned of 14489-75-9, Formula: https://www.ambeed.com/products/14489-75-9.html.
The introduction of sulfur atoms into trifluoromethylated alkenyl sulfones and chlorides were studied using a reactive sulfur-graphite electrode in N,N-dimethylformamide. A substrate, 2-(4-biphenylyl)-4,4,4-trifluoro-3-phenylsulfonyl-2-butenenitrile (1a) afforded a coupling compound bridged with a nitrogen atom of isothiazole and 1,2-dithiolane skeleton (2). 1-(4-Biphenylyl)-3,3,3-trifluoro-2-phenylsulfonylpropene (1b) without a cyano group gave a complex oligomeric compound (3) without the elimination of the phenylsulfonyl group. 2- (4-Biphenylyl)-3-chloro-4,4,4-trifluoro-2 butenenitrile (1c) having a chloro group as a leaving group gave 2,4-di (4-biphenylyl)-2,4-dicyano-1,5-bis (trifluoromethyl)-3,6-dithiabicyclo[3.1.0]hexane (4) and 2-(4-biphenylyl)-4,4,4-trifluoro-2-butenenitrile (5). Methyl 2-(4- biphenylyl)-3-chloro-4,4,4-trifluoro-2-butenoate (1d) having an ester group in the place of a cyano group afforded di-[2-(4 biphenylyl)-2-methoxycarbonyl-1 trifluoromethylethyl] disulfide (6). The formation of such sulfur-containing organofluorine compounds except for the oligomeric compound 3 is characterized as the addition of polysulfide anion(s) produced by electroreduction of elemental sulfur. followed by the elimination of the phenylsulfonyl or the chloro group.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. In my other articles, you can also check out more blogs about 14489-75-9. Formula: https://www.ambeed.com/products/14489-75-9.html.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com