Product Details of 1775-95-7, Academic researchers, R&D teams, teachers, students, policy makers and the media all rely on us to share knowledge that is reliable, accurate and cutting-edge. 1775-95-7, Name is (2-Amino-5-nitrophenyl)(phenyl)methanone, SMILES is NC1=C(C=C(C=C1)[N+]([O-])=O)C(=O)C1=CC=CC=C1, belongs to isothiazole compound. In a article, author is Banert, Klaus, introduce new discover of the category.
The synthesis of postulated 2H,6H-1,5-dithiocinesfrom isonitriles and acetylenedicarboxylates or dibenzoylacetylene in the presence of elemental sulfur was repeated. The products do not possess the structure of eight-membered sulfur heterocycles, but isothiazole3(2H)-thiones were formed instead. This structural corrigendum was confirmed not only by a critical consideration of the C-13 NMR spectroscopic data and by the correction of the MS spectra and the values of the elemental analyses but also by X-ray crystallographic structure determination. Several reaction mechanisms are discussed to explain the generation of the observed isothiazole-3(2H)-thiones.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com