Chemical Research Letters, April 2021. Healthcare careers for chemists are once again largely based in laboratories, although increasingly there is opportunity to work at the point of care, helping with patient investigation. 35285-69-9, Name is Sodium 4-(propoxycarbonyl)phenolate, molecular formula is C10H11NaO3, Recommanded Product: 35285-69-9, belongs to isothiazole compound, is a common compound. In a patnet, author is Moon, Sanghun, once mentioned the new application about 35285-69-9.
A rhodium-catalyzed oxidative annulation of benzimidates with elemental sulfur for the direct construction of isothiazole rings is reported. The proposed reaction mechanism involving Rh(I)/Rh(III) redox is supported by a stoichiometric reaction of metallacycle species as well as DFT calculations. This method is also applicable to selenium cyclization to produce isoselenazole derivatives. The alkoxy substituent at C3 can be used for further functionalization of the azole core.
Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. If you are hungry for even more, make sure to check my other article about 35285-69-9, Recommanded Product: 35285-69-9.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com