New Advances in Chemical Research in 2021, Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media. 35271-74-0, Name is 3-(4-Chlorophenyl)pentanedioic acid, molecular formula is C11H11ClO4, belongs to isothiazole compound. In a document, author is Shimada, Kazuaki, introduce the new discover, Product Details of 35271-74-0.
Treatment of substituted propargyl methyl ethers with a base and elemental sulfur in the presence of a thiolate ion afforded 2-alkenecarbodithioate esters in good yields. The reaction is assumed to proceed through a pathway involving in situ generation of propadienethione intermediates. Further conversion of 2-alkenecarbodithioate esters into 2,3-dihydroisothiazoles were efficiently performed by treating with chloramine-T through a [4+1] type oxidative ring closure via thiocarbonyl S-tosylimides.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com