New Advances in Chemical Research in 2021. Chemistry is a science major with cience and engineering. The main research directions are chemical synthesis,and research on the structure and performance of functional materials. 1775-95-7, Name is (2-Amino-5-nitrophenyl)(phenyl)methanone, molecular formula is C13H10N2O3, belongs to isothiazole compound. In a document, author is Banert, Klaus, introduce the new discover, Computed Properties of https://www.ambeed.com/products/1775-95-7.html.
The synthesis of postulated 2H,6H-1,5-dithiocinesfrom isonitriles and acetylenedicarboxylates or dibenzoylacetylene in the presence of elemental sulfur was repeated. The products do not possess the structure of eight-membered sulfur heterocycles, but isothiazole3(2H)-thiones were formed instead. This structural corrigendum was confirmed not only by a critical consideration of the C-13 NMR spectroscopic data and by the correction of the MS spectra and the values of the elemental analyses but also by X-ray crystallographic structure determination. Several reaction mechanisms are discussed to explain the generation of the observed isothiazole-3(2H)-thiones.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com