New discoveries in chemical research and development in 2021, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 151-10-0, Name is 1,3-Dimethoxybenzene, SMILES is COC1=CC(OC)=CC=C1, in an article , author is BRYCE, MR, once mentioned of 151-10-0, Quality Control of 1,3-Dimethoxybenzene.
The synthesis. X-ray crystal structure and some reactions of 1,2-dithiole-3-thione derivative 8 are reported. The structure of thione 8 is characterised by a remarkable three-dimensional network of close, non-bonded, S—S interactions. Compound 8 is efficiency converted into the 1,2-dithiolium cation salt 11 by sequential reaction with meta-chloroperoxybenzoic acid and sodium iodide. Cation salt 11 reacts with aqueous ammonia in the presence of iodine to afford isothiazole derivative 18 in high yield the mechanism proposed for this reaction proceeds via 1,2,3-dithiazine derivative 17. The solution electrochemistry of the title thione, and related compounds, has been studied by cyclic voltammetry.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 151-10-0. Quality Control of 1,3-Dimethoxybenzene.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com