Chemistry is an experimental science, Name: Sodium 4-(propoxycarbonyl)phenolate, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 35285-69-9, Name is Sodium 4-(propoxycarbonyl)phenolate, molecular formula is C10H11NaO3, belongs to isothiazole compound. In a document, author is Moon, Sanghun.
Synthesis of Isothiazoles and Isoselenazoles through Rhodium-Catalyzed Oxidative Annulation with Elemental Sulfur and Selenium
A rhodium-catalyzed oxidative annulation of benzimidates with elemental sulfur for the direct construction of isothiazole rings is reported. The proposed reaction mechanism involving Rh(I)/Rh(III) redox is supported by a stoichiometric reaction of metallacycle species as well as DFT calculations. This method is also applicable to selenium cyclization to produce isoselenazole derivatives. The alkoxy substituent at C3 can be used for further functionalization of the azole core.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 35285-69-9, in my other articles. Name: Sodium 4-(propoxycarbonyl)phenolate.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com