100-18-5, Name is 1,4-Diisopropylbenzene, molecular formula is C12H18, Computed Properties of C12H18, belongs to isothiazole compound, is a common compound. In a patnet, author is CAPUANO, L, once mentioned the new application about 100-18-5.
NEW SYNTHESES OF HETEROCYCLES WITH VINYLCARBODIIMIDES AND DIVINYLCARBODIIMIDES – PYRROLES, TRIAZOLES, PYRIMIDINES, PYRINDINES, ISOQUINOLINES AND THIAZOLYL-ISOTHIAZOLES
The title compounds 3 and 4 react with diazomethane either by loss or by retention of the diazo nitrogen, to afford 3,4-dihydro-2-imino-2H-pyrroles 6 and 10 or the vic-triazole 5, respectively. The structure of 5 has been established by X-ray diffraction analysis. – The [4 + 2] addition of benzylidene methylamine or alicyclic enamines 9 to 4 results in the formation of partially hydrogenated pyrimidine 7, pyrindine 11a or isoquinoline 11b. – Thermolysis of 4 proceeds with spontaneous dehydrogenation, giving high yields of 1-(1-indolyl) isoquinohnes 8. – The derivative 10a, when melted with sulfur, undergoes both dehydrogenation and sulfur insertion, whereby the hitherto unknown thiazolyl-isothiazole 13 is formed. Its structure has been elucidated by an X-ray diffraction analysis. – A synthesis of the imidazo[2,1-a]isoquinohne derivative 16 is reported.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com