Discovery of Isothiazole

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Preparation and Characterization of the First Isothiazolyl and Isothiazolinylidene Complexes of Gold(I)

Isothiazolyl complexes have been synthesized by the addition of isothiazol-5-yllithium to gold(I) chloride or tetrahydrothiophene(pentafluorophenyl)gold complexes.Protonation or alkylation of these isothiazolyl complexes yielded the corresponding isothiazolinylidene complexes.The mono(isothiazolyl)-aurate and mono(isothiazolinylidene) complexes undergo homoleptic rearrangement.The molecular structure of the mono(isothiazolyl) complex shows a gold-carbon bond length of 2.032(7) Angstroem.

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Reference£º
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com