Pogatchnik, Diana M.; Wiemer, David F. published the artcile< Enantioselective synthesis of α-hydroxy phosphonates via oxidation with (camphorsulfonyl)oxaziridines>, SDS of cas: 104322-63-6, the main research area is phosphonate hydroxy enantioselective preparation; hydroxylation enantioselective phosphonate oxaziridine camphorsulfonyl; chiral phosphonate hydroxy preparation.
Reaction of phosphonate anions with enantiomerically pure (camphorsulfonyl)oxaziridines gave nonracemic α-hydroxy phosphonates. This enantioselective hydroxylation methodol. provides convenient access to optically active α-hydroxy phosphonates and their corresponding phosphonic acids. E.g., treating PhCH2P(O)(OMe)2 with (Me3Si)2NNa in THF gave 70% (S)-PhCH(OH)P(O)(OMe)2 (93% ee).
Tetrahedron Letters published new progress about Hydroxylation, stereoselective. 104322-63-6 belongs to class isothiazole, and the molecular formula is C10H15NO3S, SDS of cas: 104322-63-6.
Referemce:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com