Glahsl, Gudrun; Herrmann, Rudolf published the artcile< (+)-(3-Oxocamphorsulfonyl)oxaziridine as a highly stereoselective reagent for the oxidation of sulfides to chiral sulfoxides>, HPLC of Formula: 104322-63-6, the main research area is stereoselective oxidation sulfide oxocamphorsulfonyloxaziridine; sulfoxide chiral asym synthesis; aldehyde sulfinyl chiral.
The synthesis of the title oxaziridine (I) and its application to the enantio- or diastereoselective oxidation of sulfides to sulfoxides is described. Enantiomeric excesses up to 66% are observed, showing the reagent to be superior to most other oxidizing systems. The exceedingly mild reaction conditions (aprotic, neutral) allow the preparation of several chiral α-sulfinyl aldehydes. The properties. of these compounds are discussed.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) published new progress about Stereochemistry. 104322-63-6 belongs to class isothiazole, and the molecular formula is C10H15NO3S, HPLC of Formula: 104322-63-6.
Referemce:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com