Davis, Franklin A.; Haque, M. Serajul; Ulatowski, Terrance G.; Towson, James C. published the artcile< Asymmetric oxidation of ester and amide enolates using new (camphorylsulfonyl)oxaziridines>, Formula: C10H15NO3S, the main research area is asym oxidation amide ester enolate; camphorylsulfonyloxaziridine asym oxidation; oxaziridine camphorylsulfonyl asym oxidation.
The first asym. oxidation of ester and amide lithium enolates RR1CHCOR2 (R = H, Me; R1 = Ph, PhCH2; R2 = MeO, Me3CO, pyrrolidino) to optically active α-hydroxy carbonyl compounds RR1C(OH)COR2 is reported using new, easily prepared, stable (camphorylsulfonyl)oxaziridines (+)-(2R,8aS)-I and (-)-(2S,8aR)-II. Either enantiomer of RR1C(OH)COR2 can be readily obtained because the configuration of the oxaziridine three-membered ring determines the product stereochem.
Journal of Organic Chemistry published new progress about Enols, esters Role: RCT (Reactant), RACT (Reactant or Reagent). 104322-63-6 belongs to class isothiazole, and the molecular formula is C10H15NO3S, Formula: C10H15NO3S.
Referemce:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com