Abraham, Elin; Candela-Lena, Jose I.; Davies, Stephen G.; Georgiou, Matthew; Nicholson, Rebecca L.; Roberts, Paul M.; Russell, Angela J.; Sanchez-Fernandez, Elena M.; Smith, Andrew D.; Thomson, James E. published the artcile< Asymmetric synthesis of N,O,O,O-tetra-acetyl D-lyxo-phytosphingosine, jaspine B (pachastrissamine) and its C(2)-epimer>, HPLC of Formula: 104322-63-6, the main research area is phytosphingosine jaspine B pachastrissamine amino alc asym preparation; ester unsaturated stereoselective conjugate addition oxidation intramol cyclization.
The highly diastereoselective conjugate addition of lithium (S)-N-benzyl-N-(α-methylbenzyl)amide to a γ-silyloxy-α,β-unsaturated ester and in situ enolate oxidation with (+)-(camphorsulfonyl)oxaziridine has been used as the key step in the asym. synthesis of N,O,O,O-tetra-acetyl D-lyxo-phytosphingosine I, jaspine B (pachastrissamine) II and its C(2)-epimer III.
Tetrahedron: Asymmetry published new progress about Amino alcohols, chiral Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 104322-63-6 belongs to class isothiazole, and the molecular formula is C10H15NO3S, HPLC of Formula: 104322-63-6.
Referemce:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com