The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: (1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid( cas:560-09-8 ) is researched.Related Products of 560-09-8.Zhang, Jian; Chen, Shumei; Zingiryan, Areg; Bu, Xianhui published the article 《Integrated Molecular Chirality, Absolute Helicity, and Intrinsic Chiral Topology in Three-Dimensional Open-Framework Materials》 about this compound( cas:560-09-8 ) in Journal of the American Chemical Society. Keywords: cobalt camphorate homochiral polymeric complex preparation structure; nickel camphorate homochiral polymeric complex preparation structure; benzenedicarboxylate cobalt camphorate trimethylenedipyridine polymeric complex preparation structure; indium camphorate homochiral polymeric complex preparation structure; magnesium malate polymeric complex preparation structure; crystal structure metal camphorate malate polymeric complex; chirality metal camphorate malate polymeric complex. Let’s learn more about this compound (cas:560-09-8).
While chiral materials are common, few are known that integrate mol. chirality, absolute helicity, and 3-dimensional intrinsically chiral topol. nets in one material. Such multihomochiral features may lead to enhanced chiral recognition processes that are important for enantioselective catalysis or separation Reported here are 3-dimensional open-framework materials with unusual integration of various homochiral and homohelical features, even in the bulk sample. Thus, Me4N[InL2]·2H2O (H2L = D- and L-camphoric acid (Hcam)), (Me3NCH2CH2OH)[In(D-cam)2]·2H2O, Co(D-cam)1/2(bdc)1/2(tmdpy) (H2dbc = 1,4-benzenedicarboxylic acid; tmdpy = 4,4′-trimethylenedipyridine). Ni(D-cam)(H2O)2 and Mg(L-ma)(H2O)2·H2O (L-maH2 = L-malic acid) were prepared and their crystal structures determined
After consulting a lot of data, we found that this compound(560-09-8)Related Products of 560-09-8 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com