The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: (1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid( cas:560-09-8 ) is researched.Synthetic Route of C10H16O4.Zhao, Xiang; Nguyen, Edward T.; Hong, Anh N.; Feng, Pingyun; Bu, Xianhui published the article 《Chiral Isocamphoric Acid: Founding a Large Family of Homochiral Porous Materials》 about this compound( cas:560-09-8 ) in Angewandte Chemie, International Edition. Keywords: chiral isocamphorate preparation homochiral porous material; transition metal isocamphorate camphorate MOF preparation; crystal structure magnesium cobalt copper isocamphorate camphorate MOF; camphoric acid; chiral ligands; homochiral porous materials; isocamphoric acid; metal-organic frameworks. Let’s learn more about this compound (cas:560-09-8).
Homochiral metal-organic frameworks (MOFs) are an important class of chiral solids with potential applications in chiral recognition; however, relatively few are available. Of great importance is the availability of low-cost, racemization-resistant, and versatile enantiopure building blocks. Among chiral building blocks, D-camphoric acid is highly prolific, yet, its trans-isomer, L-isocamphoric acid, has remained unknown in the entire field of solid-state materials. Its rich yet totally untapped synthetic and structural chem. has now been studied through the synthesis of a large family of homochiral metal isocamphorates. The 1st observation of diastereoisomerism in isostructural MOFs is presented. Isocamphorate has a powerful ability to create framework topologies unexpected from common inorganic building blocks, and isocamphoric acid should allow access to hundreds of new homochiral materials.
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Reference:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com