Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: (1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid, is researched, Molecular C10H16O4, CAS is 560-09-8, about Size-Selective Crystallization of Homochiral Camphorate Metal-Organic Frameworks for Lanthanide Separation.Application In Synthesis of (1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid.
Lanthanides (Ln) are a group of important elements usually found in nature as mixtures Their separation is essential for technol. applications but is made challenging by their subtly different properties. Here the authors report that crystallization of homochiral camphorate metal-organic frameworks (MOFs) is highly sensitive to ionic radii of lanthanides and can be used to selectively crystallize a lanthanide element into predesigned MOFs. Two series of camphorate MOFs were synthesized with acetate (Type 1 with early lanthanides La-Dy) or formate (Type 2 with late lanthanides Tb-Lu and Y) as the auxiliary ligand, resp. The Ln coordination environment in each type exhibits selectivity for Ln3+ of different sizes, which could form the basis for a new cost-effective method for Ln separation
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Reference:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com