Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Aluminum(III) sulfate xhydrate, is researched, Molecular Al2H8O13S3, CAS is 17927-65-0, about The thermal decomposition of aluminum sulfate in different gas phase environments.SDS of cas: 17927-65-0.
The thermal decomposition of Al2(SO4)3.xH2O was studied. The process was faster in a reducing atm. (Ar:H 95:5 volume %) but the mechanism remained constant Al2O(SO4)2 formed as intermediate in both cases. A 2-step mechanism is proposed.
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Reference:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com