Month: March 2022

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《The thermal decomposition of the hydrates, nitrates and oxide of aluminum》. Authors are Parravano, N.; Malquori, G..The article about the compound:Aluminum(III) sulfate xhydratecas:17927-65-0,SMILESS:O=S(O)(O)=O.O=S(O)(O)=O.O=S(O)(O)=O.[H]O[H].[Al].[Al]).Reference of Aluminum(III) sulfate xhydrate. Through the article, more information about this compound (cas:17927-65-0) is conveyed.

Al(NO3)3.6H2O is formed when Al(NO3)3.9H2O is maintained at ordinary temperature over P2O5 in vacuo, or by repeated treatment of Al(NO3)3.9H2O with hot HNO3.H2O. Al(NO3)3.6H2O has already been prepared in other ways (cf. Inamura, Mem. Coll. Sci. Kyoto 4, 105(1919); C. A. 14, 2451). A new hydrate, Al(NO3)3.4H2O, was prepared by maintaining Al(NO3)3.6H2O in contact with excess N2O5 at ordinary temperature for 12 h. It remains unaltered up to 180°, at which temperature it decomposes to Al2O3, N2O5 and H2O. The thermal decomposition curve of Al(NO3)3.9H2O showed breaks at 73.5°, 140° and 200°, corresponding to fusion and conversion to Al(NO3)3.6H2O, to decomposition of the latter to the basic salt, 4Al2O3.3N2O5. 14H2O, and to decomposition of the latter to Al2O3. The curve of AlCl3.6H2O showed breaks at 122° and at 180°, the latter corresponding to decomposition of Al2O3. Al2(SO4)3.18H2O behaves differently. At 105° it becomes anhydrous and at 760° the Al2(SO4)3 decomposes to Al2O3 and SO3. Samples from various sources of Al2O3 containing different proportions of H2O of hydration were then heated, and the curves were compared with those of gibbsite, diaspore and bauxite. The results were complicated and difficult of interpretation but indicate that the breaks in the curve which were observed were caused by the formation of lower hydrates of definite chem. composition and (2) by adsorption phenomena.

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Pradhananga, Trinetra M.; Matsuo, Sadao published an article about the compound: Aluminum(III) sulfate xhydrate( cas:17927-65-0,SMILESS:O=S(O)(O)=O.O=S(O)(O)=O.O=S(O)(O)=O.[H]O[H].[Al].[Al] ).Category: isothiazole. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:17927-65-0) through the article.

The D/H fractionation factors (α) of some of the sulfate hydrate-H2O systems were measured. A dependence of α on cationic parameters and M-H2O distance was found. The D/H fractionation factors of various hydrate-water systems were divided into 2 groups with respect to their α values: one having α < 1 and the other α > 1. There is almost no change in α for crystal-H2O systems having SO42- as the anion of the 1st transition metal ion series from Fe2+ to Zn2+, except for Cu2+. This is related to the common structure of the hydration sphere of cations and the common distance of M-H2O. The exceptional case for Cu2+ is attributed to the distorted structure of octahedra surrounding Cu2+. A similar type of behavior of protons leading to the residual entropy was found in some of the crystal-H2O systems having α > 1.

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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Quantum Chemistry, NMR Spectroscopy, and Single-Crystal Diffractometry Methods in the Analysis of Protonation Pathways of 2-Amino-4-benzylsulfanyl-6-methylpyrimidines, published in 2019-01-31, which mentions a compound: 6307-44-4, mainly applied to aminomethyl pyrimidinethione benzyl chloride protonation mechanism NMR chem shift, Application In Synthesis of 2-Amino-6-methylpyrimidine-4-thiol.

Protonation pathways of 2-amino-4-benzylsulfanyl-6-methylpyrimidines have been investigated by means of semiempirical PM3 quantum-chem. simulation, 13C NMR spectroscopy, and single-crystal diffractometry methods. In the gas phase and in the bipolar aprotic solvent, the protonation involves the N1 atom. The protonation in the crystalline state is characterized by the formation of a branched system of H-bonds, involving the protons of the amino group besides the mentioned nitrogen atom.

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The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Configuration of the camphoric acids》. Authors are Walker, James; Wood, John K..The article about the compound:(1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acidcas:560-09-8,SMILESS:CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O).Application of 560-09-8. Through the article, more information about this compound (cas:560-09-8) is conveyed.

The molecule of camphoric acid contains two, and only two, asymmetric carbon atoms, that these carbon atoms are links in a closed carbon chain, and that each of them has a carboxyl group attached to it. It is further known that the asymmetric carbon atoms are not similar to each other, so that there can be no optical inactivity by internal compensation. To distinguish between these two asymmetric atoms, the prefixes ortho- and allo-, which are commonly used in application to the two carboxyl groups are employed. A discussion on the asymmetric carbon atom to which the ortho-carboxyl group is attached as the ortho-carbon atom, and of that to which the allo-carboxyl group is united as the allo-carbon atom, is presented.

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The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Aluminum(III) sulfate xhydrate( cas:17927-65-0 ) is researched.Application of 17927-65-0.Lee, H. published the article 《Preparation of Ba-doped γ-Al2O3 from kaolin and its characteristics》 about this compound( cas:17927-65-0 ) in RIST Yongu Nonmun. Keywords: barium doped alumina powder thermal stability. Let’s learn more about this compound (cas:17927-65-0).

The synthesis of γ-Al2O3 powder for catalytic support from kaolin-derived Al sulfate solution was described. Al sulfate hydrate[Al2(SO4)3·nH2O] was precipitated by dropping it into Et alc. The γ-Al2O3 power was prepared by calcination of the precipitate The powder showed thermal stability after calcination at 1000° for 2 h. However, the powder calcined at 1200° for 2 h was fully transformed into γ-Al2O3. Ba-doped γ-Al2O3 samples were prepared by impregnation of γ-Al2O3 with appropriate solution concentrations(mol%) of Ba chloride [Ba]/([Ba]+[Al]). The effect of Ba addition on the thermal stability of the Ba-doped γ-Al2O3 was studied. The amount of the additive was 2-10 mol% with respect to the γ-Al2O3. The additions of 4 mol% and 8 mol% Ba were effective at 1250° and 1450° in retarding the γ-Al2O3 transition due to the formation of Ba hexaaluminate(BaAl12O19). The activation energies of the γ-Al2O3 → α-Al2O3 transition in samples with and without 4 mol% Ba-doped were calculated in accordance with the Arrhenius equation and resulted in 114.5 Kcal/mol and 137.8 Kcal/mol, resp.

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Name: 2-Amino-6-methylpyrimidine-4-thiol. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 2-Amino-6-methylpyrimidine-4-thiol, is researched, Molecular C5H7N3S, CAS is 6307-44-4, about Aryl ethers of 4-[(2-hydroxyethyl)sulfanyl]pyrimidine derivatives: Pathways of synthesis and fungicidal activity of their salt forms. Author is Erkin, A. V.; Klaptyuk, I. V.; Gurzhii, V. V.; Yuzikhin, O. S.; Krutikov, V. I..

2-Amino-4-[(2-aryloxyethyl)sulfanyl]-6-methylpyrimidines were obtained by S-alkylation of 2-amino-6-methylpyrimidin-4(3H)-thione with 2-aryloxyethyl chlorides. Since 2-amino-4-[(2-chloroethyl)sulfanyl]-6-methylpyrimidine is prone to in situ intramol. cyclization it cannot be used in Claisen reaction. The bromination of the target compounds provided 5-bromo derivatives; some of their hydrochlorides exhibited fungicidal activity.

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Liu, Yan-Song; Yu, Tim; Armstrong, Daniel W. published an article about the compound: (1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid( cas:560-09-8,SMILESS:CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O ).Safety of (1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:560-09-8) through the article.

The sensitivity and ruggedness of chiroptical detectors have improved considerably during the past decade. The authors examine >230 chiral compounds using the latest laser-based polarimetry detector for HPLC. They also examine the relation between optical rotation at the detector wavelength of 675 nm and the sodium D line. The authors consider the sensitivity, linear dynamic range, and effect of solvent composition on rotation and its general use as an HPLC detector for chiral compounds

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The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 2-(tert-Butyl)isothiazol-3(2H)-one 1,1-dioxide(SMILESS: O=C(C=C1)N(C(C)(C)C)S1(=O)=O,cas:119639-24-6) is researched.Quality Control of 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate. The article 《Isothiazolidinone heterocycles as inhibitors of protein tyrosine phosphatases: Synthesis and structure-activity relationships of a peptide scaffold》 in relation to this compound, is published in Bioorganic & Medicinal Chemistry. Let’s take a look at the latest research on this compound (cas:119639-24-6).

Oxo- and trioxo-substituted isothiazolidinylphenylalanines are prepared as tyrosine mimetics by Suzuki coupling reactions of chloroisothiazolidinones and chlorodioxoisothiazolidinones with N-Boc-4-borono-L-phenylalanine derivatives; the isothiazolidinylphenylalanines (with or without subsequent hydrogenation) are incorporated into dipeptides prepared as human protein tyrosine phosphatase 1B (PTP1B) inhibitors such as I. Of the compounds tested, I is the most potent inhibitor of PTP1B with an IC50 value of 40 nM; the corresponding mixture of isothiazolidinone diastereomers inhibits PTP1B with an IC50 value of 80 nM, and the separated (R)-isothiazolidinone diastereomer inhibits PTB1B with an IC50 value of 15.5 μM; the related dipeptides prepared inhibit PTP1B less potently than either I or the mixture of isothiazolidine diastereomers containing I. Crystal structures of a dioxothiazolidinone-substituted dipeptide and a dioxoisothiazolinone-substituted dipeptide bound to PTP1B are determined by X-ray crystallog.; the low energy conformation found by ab initio calculations for the saturated heterocycle more closely approaches the conformation obtained upon binding to PTP1B than that of the unsaturated heterocycle.

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Sychev, M. M.; Shiballo, V. G.; Katushkin, V. P.; Ustinov, A. E. published the article 《Dielectric properties of calcium, zinc, magnesium, copper, aluminum, iron, manganese, nickel, and cobalt sulfates》. Keywords: dielec constant sulfate hydrate cement.They researched the compound: Aluminum(III) sulfate xhydrate( cas:17927-65-0 ).Category: isothiazole. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:17927-65-0) here.

The dielec. constant (κ) of various sulfate hydrates of Ca2+, Zn2+, Mg2+, Cu2+, Al3+, Fe2+, Mn2+, Ni2+, and Co2+ was studied in relation to the n (number of mols. of bound water); the κ increased with an increase in n. A rectilinear equation κ = α + n × tg β is derived, where α = κ of anhydrous salt and tg β = tangent of the angle of curve κ-n. The compressive strength of cement stones, containing these crystallohydrates, decreased with an increase in tg β of the salt.

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Application In Synthesis of Aluminum(III) sulfate xhydrate. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Aluminum(III) sulfate xhydrate, is researched, Molecular Al2H8O13S3, CAS is 17927-65-0, about Increase in the hydration activity and improvement in the structural-engineering properties of slag portland cement. Author is Syrkin, Ya. M.; Shokotova, B. G.; Engorn, T. I.; Tokar, V. A.; Zubik, M. I..

The sulfate-aluminate-silicate product, obtained as a tailing in the production of Al sulfate from kaolin clays, is used as an hardening accelerator for slag portland cement. The tailings consist of amorphous SiO2, metakaolinite [15123-81-6], Al2(SO4)3.nH2O, NaAl(SO4)2.12H2O, gypsum [13397-24-5], anhydrite [14798-04-0], and some Fe and Mg sulfates. Initial and final setting times and compressive and tensile strengths are determined of slag portland cements with 1 and 3% of these tailings and those with 1% coke dust. These additives increase the hydration activity of the slag portland cement and its frost resistance and decrease the shrinkage deformation.

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