Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 560-09-8, is researched, SMILESS is CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O, Molecular C10H16O4Journal, Article, Angewandte Chemie, International Edition called Chiral Reticular Self-Assembly of Achiral AIEgen into Optically Pure Metal-Organic Frameworks (MOFs) with Dual Mechano-Switchable Circularly Polarized Luminescence, Author is Shang, Weili; Zhu, Xuefeng; Liang, Tongling; Du, Cong; Hu, Liangyu; Li, Tiesheng; Liu, Minghua, the main research direction is selfassembly achiral aggregation emitter metalorganic framework circularly polarized luminescence; aggregation-induced emission (AIE); chirality transfer; circularly polarized luminescence; mechano stimuli; metal-organic frameworks (MOFs).Related Products of 560-09-8.
Circularly polarized luminescence (CPL) is attractive in understanding the excited-state chirality and developing advanced materials. A chiral reticular self-assembly strategy to unite achiral AIEgens, chirality donors, and metal ions to fabricate optically pure AIEgen metal-organic frameworks (MOFs) as efficient CPL materials is proposed. CPL activity of the single-crystal AIEgen MOF was generated by the framework-enabled strong emission from AIEgens and through-space chirality transfer from chirality donors to achiral AIEgens via metal-ion bridges. A dual mechano-switched blue and red shifted CPL activity was achieved via ultrasonication and grinding, which enabled the rotation or stacking change of AIEgen rotors with the intact homochiral framework. This work provided not only an insightful view of the aggregation-induced emission (AIE) mechanism, but also an efficient and versatile strategy for the preparation of stimuli-responsive CPL materials.
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Reference:
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com