Recently I am researching about PD/C-CATALYZED SYNTHESIS; C-H ALKENYLATIONS; OXIDASE CATALYSIS; BOND; ALKYNES; ACTIVATION; BENZAMIDES; EFFICIENT; FUNCTIONALIZATION; AMARYLLIDACEAE, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21871187, 21572137]; Key Program of Sichuan Science, Technology Project [2019YFG0146]; Research Fund of Department of Education of Sichuan Province [18ZB0481]. Recommanded Product: 3-Methylbenzoic acid. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Sun, R; Yang, X; Li, QG; Xu, K; Tang, J; Zheng, XL; Yuan, ML; Fu, HY; Li, RX; Chen, H. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid
A simple and efficient method for the synthesis of isoquinolone and isocoumarin derivatives is reported. The method for the first time provides a one-step divergent synthesis of important isoquinolone and isocoumarin skeletons from benzoic acid by switching the coupling partners. In addition, a reliable mechanism has been proposed on the basis of experimental investigations, including kinetic isotope effect experiments, C-13 labeling experiments, time-tracking experiments, and competitive experiments, as well as DFT calculation studies.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com