Application In Synthesis of 2,5-Dimethoxybenzaldehyde. Recently I am researching about NITRILE OXIDES; 3,5-DICHLORO-2,4,6-TRIMETHYLBENZONITRILE OXIDE; ORGANOCATALYSTS; GENERATION; HYBRIDS; OXIMES; DNA, Saw an article supported by the GVK Biosciences Pvt. Ltd.. Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Swapnaja, KJM; Yennam, S; Chavali, M. The CAS is 93-02-7. Through research, I have a further understanding and discovery of 2,5-Dimethoxybenzaldehyde
A series of novel spirobiisoxazoline dibenzoquinone derivatives were synthesized starting from 2,5-dimethoxybenzaldehyde in a six-step synthetic sequence. The key step [3 + 2] double 1,3-dipolar cycloaddition of oxime chloride with allenoate was performed under mild reaction conditions using sodium carbonate at ambient temperature. This is the first innovative synthesis of Spirobiisoxazoline Dibenzoquinone system where quinone ring is alkylated to isoxazoline moiety. (C) 2018 Elsevier Ltd. All rights reserved.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com