An article Visible-light-induced dearomative oxamination of indole derivatives and dearomative amidation of phenol derivatives WOS:000553224000017 published article about PHOTOREDOX CATALYSIS; MEDIATED DEAROMATIZATION; ASYMMETRIC ALKYLATION; ELECTRON-TRANSFER; NITRENIUM ION; AZIRIDINATION; RADICALS; AZASPIROCYCLIZATION; SULFONAMIDES; REAGENTS in [Wu, Lingang; Hao, Yanan; Liu, Yuxiu; Song, Haibin; Wang, Qingmin] Nankai Univ, Res Inst Elementoorgan Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China; [Wang, Qingmin] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China in 2020.0, Cited 55.0. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. Product Details of 99-04-7
Herein, we report a protocol for visible-light-induced dearomative oxamination reactions of indole derivatives to afford functionalized spirocyclic products. These step-economical reactions, which involve C-N and C-O bond formation, feature mild conditions, a broad substrate scope, high yields, exclusive diastereoselectivity and step-economy. In addition, a similar protocol could be used to synthesize spirolactams by dearomative amidation of phenol derivatives.
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