Wu, YN; Fu, MC; Shang, R; Fu, Y in [Wu, Ya-Nan; Fu, Ming-Chen; Shang, Rui; Fu, Yao] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Urban Pollutant Convers, Anhui Prov Key Lab Biomass Clean Energy,iChEM, Hefei 230026, Peoples R China; [Shang, Rui] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan published Nickel-catalyzed carboxylation of aryl iodides with lithium formate through catalytic CO recycling in 2020.0, Cited 29.0. Formula: C8H8O2. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7.
A protocol for the Ni-catalyzed carboxylation of aryl iodides with formate has been developed with good functional group compatibility for the synthesis of a variety of aromatic carboxylic acids under mild conditions. The reaction tolerates other functionalities for cross-coupling, such as aryl bromide, aryl chloride, aryl tosylate, and aryl pinacol boronate. The reaction proceeds through a carbonylation process with in situ generated carbon monoxide in the presence of a catalytic amount of acetic anhydride and lithium formate, avoiding the use of gaseous CO. The strategy of CO recycling in catalytic amounts is critical for the success of the reaction.
Formula: C8H8O2. Welcome to talk about 99-04-7, If you have any questions, you can contact Wu, YN; Fu, MC; Shang, R; Fu, Y or send Email.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com