An article An Efficient Metal-Free Oxidative Esterification and Amination of Benzyl C-H Bond WOS:000531833400052 published article about CATALYTIC AMOUNTS; ACETOXYLATION; ACIDS in [Liu, Saiwen; He, Guowen; Zhang, Jin] Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Peoples R China; [Chen, Ru] Yiyang Agr Prod Qual Detect Ctr, Yiyang 413000, Peoples R China in 2020, Cited 30. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. Application In Synthesis of 3-Methylbenzoic acid
An esterification and amination of benzylic C-H bonds was developed by using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) under metal- and iodide-free conditions. Both carboxylic acids and amines could be used as ideal coupling partners for the oxidative coupling reactions with various diarylmethanes. A close to equal amount of coupling reagents was enough to afford the product in good to high yields.
Application In Synthesis of 3-Methylbenzoic acid. About 3-Methylbenzoic acid, If you have any questions, you can contact Liu, SW; Chen, R; He, GW; Zhang, J or concate me.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com