An article Nickel-Catalyzed Homocoupling of (Z)-beta-Iodoenol Esters: Stereoselective Access to (Z,Z)-Buta-1,3-diene-1,4-diyl Diesters WOS:000477973200009 published article about ENOL ESTERS; ASYMMETRIC HYDROGENATION; CARBOXYLIC-ACIDS; VINYL HALIDES; ENANTIOSELECTIVE HYDROGENATION; STEREOSPECIFIC PREPARATION; COUPLING REACTION; IN-SITU; LIGANDS; ALKYNES in [Francos, Javier; Cadierno, Victorio] Univ Oviedo, IUQOEM, Dept Quim Organ & Inorgan,Unidad Associada CSIC, Ctr Innovac Quim Avanzada ORFEO CINQA,Lab Comp Or, Julian Claveria 8, E-33006 Oviedo, Spain in 2019.0, Cited 74.0. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. Application In Synthesis of 3-Methylbenzoic acid
A straightforward and broad-scope procedure to obtain symmetrically substituted buta-1,3-diene-1,4-diyl diesters, based on the homocoupling of the corresponding (Z)-beta-iodoenol esters, is presented. It involves the use of a catalytic system composed of [NiCl2(PPh3)(2)] (10 mol%), NaI (10 mol%), and excess of Zn dust. The reactions proceed in THF at room temperature with exquisite preservation of the stereochemistry of the C=C bond of the starting iodoolefins, thus leading to the final dienes as the correspondingZ,Z-stereoisomers exclusively.
Application In Synthesis of 3-Methylbenzoic acid. Bye, fridends, I hope you can learn more about C8H8O2, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com