Recently I am researching about FLUORIDE-MEDIATED CARBOXYLATION; C-H SILYLATION; ESTERS; CO2; REAGENTS; ALKYNES, Saw an article supported by the Japan Society for the Promotion of Science (JSPS), Global COE Program, The University of Tokyo, MEXT, Japan; Japan Science and Technology Agency (JST)Japan Science & Technology Agency (JST); Japan Agency for Medical Research and Development (AMED)Japan Agency for Medical Research and Development (AMED). Published in CHEMICAL SOC JAPAN in TOKYO ,Authors: Yoo, WJ; Kondo, J; Kobayashi, S. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid. COA of Formula: C8H8O2
A mild synthetic protocol for the preparation of aryl and alkenyl carboxylic acids was developed through a copper-catalyzed carboxylation reaction of organosilanes with carbon dioxide. The key to this process was the fine-tuning of the reactivity and selectivity of the organometallic nucleophile through structural modifications of the silane.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com