An article Hydrogen Bond Directed ortho-Selective C-H Borylation of Secondary Aromatic Amides WOS:000476294600001 published article about TRANSITION-METAL CATALYSIS; NONCOVALENT INTERACTIONS; ARENES; LIGAND; ACTIVATION; HYDROFORMYLATION; CONSTRUCTION; HETEROARENES; INSIGHTS; PHENOLS in [Bai, Shao-Tao; Bheeter, Charles B.; Reek, Joost N. H.] Univ Amsterdam, Vant Hoff Inst Mol Sci HIMS, Supramol & Homogeneous Catalysis Grp, Sci Pk 904, NL-1098 XH Amsterdam, Netherlands in 2019, Cited 76. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. Safety of 3-Methylbenzoic acid
Reported is an iridium catalyst for ortho-selective C-H borylation of challenging secondary aromatic amide substrates, and the regioselectivity is controlled by hydrogen-bond interactions. The BAIPy-Ir catalyst forms three hydrogen bonds with the substrate during the crucial activation step, and allows ortho-C-H borylation with high selectivity. The catalyst displays unprecedented ortho selectivities for a wide variety of substrates that differ in electronic and steric properties, and the catalyst tolerates various functional groups. The regioselective C-H borylation catalyst is readily accessible and converts substrates on gram scale with high selectivity and conversion.
Safety of 3-Methylbenzoic acid. Welcome to talk about 99-04-7, If you have any questions, you can contact Bai, ST; Bheeter, CB; Reek, JNH or send Email.
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