An article Nitroxyl Catalysts for Six-Membered Ring Bromolactonization and Intermolecular Bromoesterification of Alkenes with Carboxylic Acids WOS:000643163800004 published article about ASYMMETRIC ALLYLATION; ENANTIOSELECTIVE ALLYLATION; N-OXIDE; ALDEHYDES; BROMOCYCLIZATION; ORGANOCATALYSTS; HALOGENATION; OXIDATION; ALLYLTRICHLOROSILANES; N,N’-DIOXIDE in [Moriyama, Katsuhiko; Kuramochi, Masako; Fujii, Kozo; Morita, Takeshi] Chiba Univ, Grad Sch Sci, Dept Chem, Chiba 2638522, Japan; [Moriyama, Katsuhiko; Kuramochi, Masako; Fujii, Kozo; Morita, Takeshi] Chiba Univ, Soft Mol Activat Res Ctr, Chiba 2638522, Japan; [Tsuzuki, Seiji] Natl Inst Adv Ind Sci & Technol, Nanosyst Res Inst NRI, Res Initiat Computat Sci RICS, Ibaraki 3058568, Japan in 2021.0, Cited 70.0. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. Safety of 3-Methylbenzoic acid
We developed a nitroxyl-catalyzed bromoesterification of alkenes with bromo reagents, which includes a six-membered ring bromolactonization of alkenyl carboxylic acids catalyzed by AZADO as the nitroxyl radical catalyst, and an intermolecular bromoesterification of alkenes with carboxylic acids using NMO as the N-oxide catalyst. We also accomplished a remote diastereoselective bromohydroxylation via an AZADO-catalyzed six-membered ring bromolactonization and a subsequent ring cleavage reaction with alkylamines to furnish epsilon-bromo-delta-hydroxy amides with high diastereoselectivity.
Safety of 3-Methylbenzoic acid. Welcome to talk about 99-04-7, If you have any questions, you can contact Moriyama, K; Kuramochi, M; Tsuzuki, S; Fujii, K; Morita, T or send Email.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com