Recently I am researching about COUPLING REACTIONS; OLEFINS; ANHYDRIDES; ACYL; DICARBOFUNCTIONALIZATION; TETRAPHENYLBORATE; RELEVANCE; STRATEGY; STEP, Saw an article supported by the NSFNational Science Foundation (NSF) [CHE-1352080]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Kadam, AA; Metz, TL; Qian, YQ; Stanley, LM. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid. Name: 3-Methylbenzoic acid
The nickel-catalyzed intermolecular carboacylation of alkenes with amides and tetraarylborates is presented. Bicyclic alkenes are readily functionalized with a variety of N-benzoyl-N-phenylbenzamides and triarylboranes, which are generated in situ from the corresponding tetraarylborates, to synthesize ketone products in up to 91% yield. Preliminary mechanistic studies suggest that migratory insertion precedes transmetalation and that reductive elimination is the turnover-limiting step. These reactions occur with excellent chemoselectivity and diastereoselectivity in the absence of a directing/chelating group and further demonstrate amides as practical acyl electrophiles for alkene dicarbofunctionalization reactions.
Name: 3-Methylbenzoic acid. Welcome to talk about 99-04-7, If you have any questions, you can contact Kadam, AA; Metz, TL; Qian, YQ; Stanley, LM or send Email.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com